Pd Supported on Pr-Rich Cerium–Zirconium–Praseodymium Mixed Oxides for Propane and CO Oxidation
نویسندگان
چکیده
The activity of emission control catalysts must be improved in urban mode at low temperatures. One possible way is to tailor the metal-support interaction between platinum group metals (PGMs) and ceria stabilize small clusters or single atoms, optimizing utilization costly PGMs. In this study, a loading Pd (<0.2 wt.%) was dispersed on Pr-rich cerium–zirconium–praseodymium mixed oxides (CZP45: Ce0.45Zr0.10Pr0.45O2−x). After initial calcination 800 °C, mainly form isolated cations which were found efficient for low-temperature CO oxidation but inactive propane combustion. Nevertheless, pre-reduction step can trigger formation nanoparticles promote oxidation. nanoparticles, formed during reduction step, coupled with high oxygen mobility CZP45, lead outstanding catalytic starting from 250 °C. However, re-oxidation their partial re-dispersion, promoted by fast oxide, rapidly deactivate lean conditions.
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ژورنال
عنوان ژورنال: Catalysts
سال: 2022
ISSN: ['2073-4344']
DOI: https://doi.org/10.3390/catal12080827